Gellan gum/bacterial cellulose hydrogel crosslinked with citric acid as an eco-friendly green adsorbent for safranin and crystal violet dye removal

Abstract

In this study, ex-situ crosslinked gellan gum (GG)/bacterial cellulose (BC) hydrogels have been investigated as good absorbents for the removal of safranin and crystal violet dye pollutants. The preparation involves a cost-effective and easy-to-perform crosslinking procedure, using citric acid (CA) as a green crosslinker. The physicochemical and mechanical properties of the crosslinked hydrogels were examined by FTIR, TGA, SEM, XRD, and unconfined compression analyses. The swelling capacity of the hydrogels as a function of pH was investigated. CA depicted to improve structural stability as a crosslinker. The dye removal capacity of the hydrogels as good adsorbents was explored and showed higher efficiency in the removal of safranin dye as compared to crystal violet with optimum adsorption capacities obtained as 17.57 and 13.49 mg/g, respectively. Adsorption kinetics and isotherm models as well as thermodynamics examined. Results showed the adsorption process well fitted the pseudo 2nd-order kinetic and Langmuir-Freundlich models while temperature dependence study depicted to be exothermic. Furthermore, no significant loss of removal efficiency of the hydrogel adsorbent was observed even after five adsorption-desorption cycles. Based on the revealed results, the prepared hydrogel may serve as an effective adsorbent for the removal of dyes from the aqueous phase. © 2022 Elsevier B.V.