Development of a catalytic model system using nitrous oxide

Beltrán-Prieto, Juan Carlos; Kolomazník, Karel

dc.title	Development of a catalytic model system using nitrous oxide	en
dc.contributor.author	Beltrán-Prieto, Juan Carlos
dc.contributor.author	Kolomazník, Karel
dc.relation.ispartof	WSEAS Transactions on Environment and Development
dc.identifier.issn	1790-5079 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued	2018
utb.relation.volume	14
dc.citation.spage	256
dc.citation.epage	262
dc.type	article
dc.language.iso	en
dc.publisher	World Scientific and Engineering Academy and Society
dc.relation.uri	http://www.wseas.org/multimedia/journals/environment/2018/a515915-014.php
dc.subject	1,2,3 propanotriol	en
dc.subject	Control	en
dc.subject	Dihydroxypropanal	en
dc.subject	Mathematical model	en
dc.subject	Nitrous oxide	en
dc.subject	Oxidation	en
dc.description.abstract	Currently, special attention is paid to partial oxidation of several sugar alcohols because it generates oxidation intermediate products with high utility value. In the present paper, we study the modelling of oxidation reaction of 1,2,3 propanotriol using an oxidizing agent in low concentrations. A major problem of such oxidation system is its low reactivity and high oxidation reactivity of products, As a result, the yield to a specific compound (i.e. dihydroxypropanal) depends on the ratio of rate constants of the consecutive reactions and also on the initial concentration of oxidizing agent. In this case, as the input value for the model calculations we chose a ratio of values of the specified rate constants and initial concentrations of nitrous oxide and 1,2,3-propanotriol. Accordingly, an experimental setup was proposed to follow the variation of temperature of the reaction blend after gradual addition of ammonium nitrate to a solution of 1,2,3 propanotriol, which can provide insights for the control of the chemical reactor. © 2018, World Scientific and Engineering Academy and Society. All Rights Reserved.	en
utb.faculty	Faculty of Applied Informatics
dc.identifier.uri	http://hdl.handle.net/10563/1007887
utb.identifier.obdid	43878647
utb.identifier.scopus	2-s2.0-85045054401
utb.source	j-scopus
dc.date.accessioned	2018-04-23T15:01:50Z
dc.date.available	2018-04-23T15:01:50Z
dc.description.sponsorship	LO1303, MŠMT, Ministerstvo Školství, Mládeže a Tělovýchovy
dc.rights	Attribution 4.0 International
dc.rights.uri	https://creativecommons.org/licenses/by/4.0/
dc.rights.access	openAccess
utb.ou	CEBIA-Tech
utb.contributor.internalauthor	Beltrán-Prieto, Juan Carlos
utb.contributor.internalauthor	Kolomazník, Karel
utb.fulltext.affiliation	JUAN CARLOS BELTRAN-PRIETO, KAREL KOLOMAZNIK Faculty of Applied Informatics Tomas Bata University in Zlín Nám. T. G. Masaryka 5555, 760 01 Zlín CZECH REPUBLIC [email protected]
utb.fulltext.dates	-
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utb.fulltext.sponsorship	This work was supported by the Ministry of Education, Youth and Sports of the Czech Republic within the National Sustainability Programme project No. LO1303 (MSMT7778/2014).
utb.scopus.affiliation	Faculty of Applied Informatics, Tomas Bata University in Zlín, Nám. T. G. Masaryka 5555, Zlín, Czech Republic
utb.fulltext.projects	LO1303 (MSMT7778/2014)