High sensitivity sensor development for hexamethylphosphoramide by polyaniline coated polyurethane membrane using resistivity assessment technique

Abstract

Hexamethylphosphoramide is considered as one of the harmful of all carcinogens. In the present work, detection of Hexamethylphosphoramide by using a polyaniline coated polyurethane membrane was carried out and device is constructed to show its practical application using resistivity assessment technique. Polyurethane nanofiber membrane was prepared by electrospinning process. A modified synthetic method used to coat polyaniline onto a polyurethane membrane found to be effective to prepare a uniform and electrically conductive coating and promising for sensing a carcinogen like Hexamethylphosphoramide. Sensing performance may be attributed to the large resistance change in polyaniline because of the deprotonation when exposed to the Hexamethylphosphoramide environment. However, it is interesting to know that the high sensitivity of polyaniline modified polyurethane membrane toward Hexamethylphosphoramide is used as a promising gas sensor for the detection of said carcinogen using resistivity assessment technique at room temperature. © 2016 Elsevier Ltd. All rights reserved.